You can add additional custom menu entries by editing /etc/grub.d/40_custom and re-generating /boot/grub/grub.cfg. Or you can create /boot/grub/custom.cfg and add them there. Changes to /boot/grub/custom.cfg do not require re-running grub-mkconfig, since /etc/grub.d/41_custom adds the necessary source statement to the generated configuration file.
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